Alas, he'll never be the man of 1004 holds...
http://www.wwe.com/videos/chris-jericho-reveals-himself-as-the-man-of-1004-holds-nitro-march-30-1998-26013703
You're right. The other divas were pre-NXT. Natty can definitely wrestle though so I'd be interested to see her with some other people who can work.
Last great divas match I can remember was Trish/Victoria/Jazz at Wrestlemania 19.
Aren't all of the current main roster Divas former NXT divas? Why is this so much better? Though I'm sure some of it can be attributed to them actually getting time to wrestle.